Ricardo, you keep saying NVME - is it really an NVME? I'm thinking you are attaching an NVME drive into a USB enclosure - if so, what you are posting isn't correct. If I'm right, you are actually trying to boot Windows from a USB drive and that isn't supported (unless you want to get into...
You very rarely need to. Key point is just because you are a member of the Adminstrator's group certainly does not mean what you are running are running with Admin. The first thing that starts is your desktop. You start everything from there. It does NOT run with Admin no matter who you are...